Of course you can scedule to record radio program. What kind of radio you wanna to record?

Is it an internet stream? If yes, do you want to capture streaming radio without losing any quality or you don't mind to record from your sound card? What stream format and protocol this streaming radio uses?

Is it a talk radio program? Or do you wanna record music splitting and tagging songs automatically?

The Streaming radio capturing software chart contains scheduling column, so you can choose a streaming audio ripper that will be able to schedule your recordings.

One of the programs that can record anything from your sound card as well as capture streaming audio/video is Replay AV. It supports advanced scheduling: you can schedule Replay AV to record at a particalar date or say every friday or weekend.